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Product Name |
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Product Type |
CYCLOHEXYLAMINE FOR SYNTHESIS 99% |
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Revised date |
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Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Stock Point : Mumbai, Kandla, Chennai, Visakhapatnam, Kolkata, Fujairah, Muscat Barka
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Phone |
+91 22 27815541 / 42 |
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Fax |
+91 22 2781 1318 :::AOH :0091 9821214367 |
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Email |
mail@rxmarine.com |
Substance / Preparation : cyclohexylamine
CAS No :108-91-8
Substance.
Substance name Contents CAS No
cyclohexylamine : 100 % 108-91-8
Contains no other components or impurities which will influence the classification of the
product.
3.1. Classification of the substance or mixture
Classification EC 67/548 or EC 1999/45
Classification : R10
Repr. Cat. 3; R62
Xn; R21/22
C; R34
Hazard Class and Category Code(s), Regulation (EC) No 1272/2008 (CLP)
Health hazards : Reproductive toxicity - Fertility - Category 2 - Warning (CLP : Repr.
2) H361
Skin corrosion - Category 1B - Danger (CLP : Skin Corr. 1B) H314
Serious eye damage - Category 1 - Danger (CLP : Eye Dam. 1) H318
Acute toxicity, dermal - Category 4 - Warning (CLP : Acute Tox. 4) H312
Acute toxicity, Oral - Category 4 - Warning (CLP : Acute Tox. 4) H302
Physical hazards : Flammable liquids - Category 3 - Warning (CLP : Flam. Liq.3) H226
3.2. Label elements
Labelling EC 67/548 or EC 1999/45
Symbol(s) : C : Corrosive
R Phrase(s) : R10 : Flammable.
R21/22 : Harmful in contact with skin and if swallowed.
R34 : Causes burns.
R62 : Possible risk of impaired fertility.
S Phrase(s) : S1/2 : Keep locked up and out of reach of children.
S26 : In case of contact with eyes, rinse immediately with plenty of water and seek
medical advice.
S36/37/39 : Wear suitable protective clothing, gloves and eye/face protection.
S45 : In case of accident or if you feel unwell, seek medical advice immediately (show
the label when possible).
Labelling Regulation EC 1272/2008 (CLP)
Hazard pictograms
Signal words : Danger
Hazard statements : H226 : Flammable liquid and vapour.
H314 : Causes severe skin burns and eye damage.
H361f : Suspected of damaging fertility.
H302 : Harmful if swallowed.
H312 : Harmful in contact with skin.
Precautionary statements
• General : P102: Keep out of reach of children.
P103: Read label before use.
P101: If medical advice is needed, have product container or label at hand.
P201: Obtain special instructions before use.
• Prevention : P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof electrical, ventilating, lighting, …, equipment.
P210: Keep away from heat, sparks, open flames or hot surfaces. – No smoking.
P280: Wear protective gloves, protective clothing, eye protection, face protection.
P260: Do not breathe dust, fume, gas, mist, vapours, spray.
P233: Keep container tightly closed.
P264: Wash thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
• Response : P302+P352: IF ON SKIN : Wash with plenty of soap and water.
P301+P330+P331: IF SWALLOWED : Rinse mouth. Do NOT induce vomiting.
P308+P313: If exposed or concerned : get medical advice.
P305+P351+P338: IF IN EYES : Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P303+P361+P353: IF ON SKIN (or hair) : Remove immediately all contaminated
clothing. Rinse skin with water/shower.
P363: Wash contaminated clothing before reuse.
P370+P378: In case of fire: Use for extinction.
• Storage : P403+P235: Store in well-ventilated place. Keep cool.
P405: Store locked up.
• Disposal considerations : P501: Dispose of this material and its container to hazardous
or special waste collection point, in accordance with local, regional, national and/or
international regulation.
3.3. Other hazards
Other hazards : The substance does not fulfil the criteria to be identified as PBT
substance or vPvB substance according to Annex XIII of Regulation REACH.
.
4.1. Description of first aid measures
Inhalation : Immediately call a POISON CENTER or doctor. Remove to fresh air and
keep at rest in a position comfortable for breathing.
Skin contact : Specific treatment (see on this label). Wash contaminated clothing before
reuse. Immediately call a POISON CENTER or doctor. Wash with plenty of soap
and water. Remove/Take off immediately all contaminated clothing.
Eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Immediately call a POISON CENTER or
doctor.
Ingestion : Rinse mouth. Do NOT induce vomiting. Immediately call a POISON
CENTER or doctor.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms relating to use : Causes severe skin burns and eye damage.
Causes serious eye damage. Suspected of damaging fertility.
Repeated exposure to this material can result in absorption through skin causing
significant health hazard.
Swallowing a small quantity of this material will result in serious health hazard.
4.3. Indication of any immediate medical attention and special treatment needed
General information : Never give anything by mouth to an unconscious person.
If exposed or concerned : get medical advice.
5.1. Extinguishing media
Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media : Do not use a heavy water stream.
Surrounding fires : Use water spray or fog for cooling exposed containers.
5.2. Special hazards arising from the substance or mixture
Hazardous combustion products : Under fire conditions, hazardous fumes will be
present. Thermal decomposition generates : Corrosive vapours.
5.3. Advice for fire-fighters
Protection against fire : Do not enter fire area without proper protective equipment,
including respiratory protection.
Special procedures : Exercise caution when fighting any chemical fire. Avoid (reject)
fire-fighting water to enter environment.
6.1. Personal precautions, protective equipment and emergency procedures
For emergency responders : Equip cleanup crew with proper protection.
Ventilate area.
Technical measures : Use special care to avoid static electric charges.
Special precautions : Remove ignition sources. No naked lights. No smoking.
For non-emergency personnel : Evacuate unnecessary personnel.
6.2. Environmental precautions
Environmental precautions : Prevent entry to sewers and public waters. Notify
authorities if product enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
Clean up methods : Soak up spills with inert solids, such as clay or diatomaceous earth
as soon as possible. Collect spillage. Store away from other materials.
6.4. Reference to other sections
See section 8. Exposure controls/personal protection
7.1. Precautions for safe handling
Handling : Handle empty containers with care because residual vapours are flammable.
Do not eat, drink or smoke when using this product. Obtain special instructions before
use. Take precautionary measures against static discharge. Wash contaminated clothing
before reuse. Wash thoroughly after handling. Do not breathe dust, fume, gas, mist,
vapours, spray.
Technical protective measures : Provide good ventilation in process area to prevent
formation of vapour. Proper grounding procedures to avoid static electricity should be
followed. Use explosion-proof electrical, ventilating, lighting, …, equipment. Use only
nonsparking tools.
Special precautions : No naked lights. No smoking.
7.2. Conditions for safe storage, including any incompatibilities
Storage : Keep only in the original container in a cool, well ventilated place. Keep in
fireproof place. Ground/bond container and receiving equipment. Keep container tightly
closed.
Storage regulation : Comply with applicable regulations.
Storage - away from : Strong bases. Strong acids. Sources of ignition. Direct sunlight.
Heat sources.
7.3. Specific end use(s)
Specific end use(s) : None.
8.1. Exposure controls
Personal protection : Avoid all unnecessary exposure.
• Respiratory protection : Wear approved mask.
• Hand protection : Wear protective gloves.
• Skin protection : Wear suitable protective clothing.
• Eye protection : Chemical goggles or face shield.
• Others : When using, do not eat, drink or smoke.
8.2. Control parameters
Occupational Exposure Limits : No data available.
9.1. Information on basic physical and chemical properties
Physical state at 20 °C : Liquid.
Odour threshold : No data available.
pH value : No data available.
Melting point [°C] : -17 °C
Decomposition point [°C] : N/A
Critical temperature [°C] : N/A
Auto-ignition temperature [°C] : N/A
Flammability (solid, gas) : N/A
Flammable liquid and vapour.
Flash point [°C] : 27 °C
Boiling point [°C] : 134 °C
Initial boiling point [°C] : N/A
Final boiling point [°C] : N/A
Evaporation rate : N/A
Vapour pressure [20°C] : 10 mm Hg @ 200C
Vapour pressure mm/Hg : 10 mm Hg @ 200C
Vapour density : 3,42
Density [g/cm3] : 0,8647
Relative density, gas (air=1) : N/A
Relative density, liquid (water=1) : N/A
Solubility in water [% weight] : Soluble
Solubility in water : N/A
Log Pow octanol / water at 20°C : No data available.
Solubility : N/A
Viscosity at 40°C [mm2/s] : N/A
9.2. Other information
Explosive properties : N/A
Explosion limits - upper [%] : 9,40%
Explosion limits - lower [%] : 1,60%
Oxidising properties : No data available.
10.1. Reactivity
Reactivity : Not established.
10.2. Chemical stability
Chemical stability : Stable under recommended storage conditions.
10.3. Possibility of hazardous reactions
Hazardous reactions : Not established.
10.4. Conditions to avoid
Conditions to avoid : Direct sunlight. Extremely high or low temperatures.
Open flame. Overheating. Heat. Sparks.
10.5. Incompatible materials
Materials to avoid : Strong acids. Strong bases.
10.6. Hazardous decomposition products
Hazardous decomposition products : Fumes. Carbon monoxide. Carbon dioxide.
Thermal decomposition generates : Corrosive vapours. May release flammable gases.
11.1. Information on toxicological effects
Acute toxicity
• Inhalation : Based on available data, the classification criteria are not met.
• Dermal : Harmful in contact with skin.
• Ingestion : Harmful if swallowed.
Corrosion : Causes severe skin burns and eye damage.
Causes serious eye damage.
Irritation : Based on available data, the classification criteria are not met.
Sensitization : Based on available data, the classification criteria are not met.
Mutagenicity : Based on available data, the classification criteria are not met.
Carcinogenicity : Based on available data, the classification criteria are not met.
Toxic for reproduction : Suspected of damaging fertility.
STOT-single exposure : Based on available data, the classification criteria are not met.
STOT-repeated exposure : Based on available data, the classification criteria are not
met
. Aspiration hazard : Based on available data, the classification criteria are not met.
12.1. Toxicity
Toxicity information : Not established.
12.2. Persistence - degradability
Persistence - degradability : Biodegradable.
12.3. Bioaccumulative potential
Bioaccumulative potential : Not established.
12.4. Mobility in soil
Mobility in soil : Not established.
12.5. Results of PBT and vPvB assessment
Results of PBT and vPvB assessment : The substance does not fulfil the criteria to be
identified as PBT substance or vPvB substance according to Annex XIII of Regulation
REACH.
12.6. Other adverse effects
Environmental precautions : Avoid release to the environment.
13.1. Waste treatment methods
General : Avoid release to the environment. Dispose in a safe manner in accordance with
local/national regulations.
Dispose of this material and its container to hazardous or special waste collection
point, in accordance with local, regional, national and/or international regulation.
Special precautions : Handle empty containers with care because residual vapours are
flammable.
14.1. Land transport (ADR-RID)
Proper shipping name : CYCLOHEXYLAMINE
UN N° : 2357 H.I. nr : 83
ADR - Class : 8
Labelling - Transport : 8 : Corrosive substance. 3 : Flammable liquid.
ADR - Classification code : CF1
ADR - Group : II
ADR - Packing instructions : P001
ADR - Limited Quantity : 1 L
ADR - Tunnel code : D/E : Bulk or tank carriage: Passage forbidden through tunnels of
category D and E. Other carriage: Passage forbidden through tunnels of category E.
14.2. Sea transport (IMDG) [English only]
Proper shipping name : CYCLOHEXYLAMINE
UN N° : 2357
IMO-IMDG - Class or division : 8 : Corrosive substance. ( 3 : Flammable liquid. )
IMO-IMDG - Packing group : II
IMO- IMDG - Packing instructions : P001
IMO-IMDG - Limited quantities : 1 L
IMO-IMDG - Marine pollution : No
EMS-Nr : F-E S-C
14.3. Air transport (ICAO-IATA) [English only]
Proper shipping name : CYCLOHEXYLAMINE
UN N° : 2357
IATA - Class or division : 8 : Corrosive substance. ( 3 : Flammable liquid. )
IATA - Packing group : II
IATA - Passenger and Cargo Aircraft : ALLOWED
- Passenger and Cargo - Packing : 851
instruction
- Passenger and Cargo - Maximum : 1 L
Quantity/Packing
IATA - Cargo only : ALLOWED
- Cargo only - Packing instruction : 855
- Cargo only - Maximum Quantity/ : 30 L
Packing
IATA - Limited Quantites : 0.5 L
ERG-Nr : 8F
15.1. Safety, health and environmental regulations/legislation specific for the
substance or mixture
Safety, health and environmental : Ensure all national/local regulations are observed.
regulations/legislation specific for the substance or mixture
REACH Restrictions - Annex XVII : The components of this product are not subject to
restrictions.
REACH Authorisation - Annex XIV : The components of this product are not subject
to authorization.
15.2. Chemical Safety Assessment
Chemical Safety Assessment : It has not been carried out.
Abbreviations and acronyms : PBT: persistent, bioaccumulative and toxic.
vPvB: very persistent and very bioaccumulative
Sources of key data used : REGULATION (EC) No 1272/2008 OF THE EUROPEAN
PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification,
labelling and packaging of substances and mixtures, amending and repealing Directives
67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006
Further information : None.
In accordance with REACH Regulation (CE) Nº 1907/2006 and with CLP Regulation
(CE) Nº 1272/2008
DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.
